| 2003— | Vice-Chairman, 10th CPPCC, National Committee | |
| 2002—2007 | Member, 16th CPC, Central Committee | |
| 1998—2003 | Vice-Chairman, 9th CPPCC, National Committee | |
| 1997—2002 | Member, 15th CPC, Central Committee | |
| 1994—1998 | President, National School of Administration | |
| 1992—1997 | Member, 14th CPC, Central Committee | |
| 1988—1998 | State Councilor, State Council | |
| 1988—1993 | Governor, People's Bank of China | |
| 1987—1992 | Member, 13th CPC, Central Committee | |
| 1986—1988 | Secretary, CPC, Provincial Committee Anhui Province |
| 05/30/07 | Li Guixian met with Russian Foreign Minister Sergei Lavrov. |
| 08/27/04 | Li Guixian held talks with Leonid Drachevsky, Russian President's Representative to the Siberian federal district. |
| 06/14/04 | Li Guixian met with Abdul Salam Majali, head of the World Affairs Council, vice president of Senate and former prime minister of Jordan. |
| 11/27/03 | Li Guixian attended the second meeting of the China-Russia financial cooperation forum. |
| 11/17/03 | Li Guixian met with Ruprecht Polenz, member of the Foreign Affairs Committee of the Federal Assembly of Germany and former secretary-general of the German Christian Democratic Union (CDU). |